Unveiling the nature of atomic defects in graphene on a metal surface

• Karl Rothe,
• Nicolas Néel and
• Jörg Kröger

Beilstein J. Nanotechnol. 2024, 15, 416–425, doi:10.3762/bjnano.15.37

• of defects. Experimental A combined STM-AFM was operated in ultrahigh vacuum (5 × 10−9 Pa) and at low temperature (5 K). Surfaces of Ir(111) were cleaned by Ar+ ion bombardement and annealing. The epitaxial growth of graphene proceeded by exposing the heated (1300 K) Ir(111) surface to the gaseous

Modulated critical currents of spin-transfer torque-induced resistance changes in NiCu/Cu multilayered nanowires

• Mengqi Fu,
• Roman Hartmann,
• Julian Braun,
• Sergej Andreev,
• Torsten Pietsch and
• Elke Scheer

Beilstein J. Nanotechnol. 2024, 15, 360–366, doi:10.3762/bjnano.15.32

• of STT-assisted resistance switching in multilayered nanowires, raw data before the background subtraction, a schematic diagram of the four-point measurements at low temperature, 2D color maps of (dV/dI)red over a larger current range and under upsweep of the magnetic field, the potential influence

Design, fabrication, and characterization of kinetic-inductive force sensors for scanning probe applications

• August K. Roos,
• Ermes Scarano,
• Elisabet K. Arvidsson,
• Erik Holmgren and
• David B. Haviland

Beilstein J. Nanotechnol. 2024, 15, 242–255, doi:10.3762/bjnano.15.23

• August K. Roos Ermes Scarano Elisabet K. Arvidsson Erik Holmgren David B. Haviland Department of Applied Physics, KTH Royal Institute of Technology, Hannes Alfvéns väg 12, SE-114 19 Stockholm, Sweden 10.3762/bjnano.15.23 Abstract We describe a transducer for low-temperature atomic force

• the internal losses. To decrease η while remaining overcoupled, the shunt inductor Ls should satisfy 50 Ω > iωcLs > R. As a final consideration, the temperature when operating low-temperature AFMs is typically around 1 K. For temperatures closer to Tc, the internal losses of the microwave circuit

• described our approach to designing cantilever force sensors with integrated microwave cavity electromechanical sensing of flexural motion, based on the strain-dependent kinetic inductance of a superconducting nanowire. This type of force sensor is potentially interesting for low-temperature AFM as the

Influence of conductive carbon and MnCo₂O₄ on morphological and electrical properties of hydrogels for electrochemical energy conversion

• Sylwia Pawłowska,
• Karolina Cysewska,
• Yasamin Ziai,
• Jakub Karczewski,
• Piotr Jasiński and
• Sebastian Molin

Beilstein J. Nanotechnol. 2024, 15, 57–70, doi:10.3762/bjnano.15.6

• elevated temperatures at the synthesis stage, which is an essential step in most of the conventional synthesis paths of conductive hydrogels described in the literature [23][24][26][27][28]. These two features, the one-stage process, and the low-temperature needed, are used for synthesising the polymer

Low temperature atomic layer deposition of cobalt using dicobalt hexacarbonyl-1-heptyne as precursor

• Mathias Franz,
• Mahnaz Safian Jouzdani,
• Lysann Kaßner,
• Marcus Daniel,
• Frank Stahr and
• Stefan E. Schulz

Beilstein J. Nanotechnol. 2023, 14, 951–963, doi:10.3762/bjnano.14.78

• saturation behaviour of the process was investigated. X-ray photoelectron spectroscopy measurements could show that the deposited cobalt is in the metallic state. The finally established process in ALD mode shows a homogeneous coating at the wafer level. Keywords: atomic layer deposition (ALD); cobalt; low

• -temperature ALD; PEALD; plasma-enhanced ALD; XPS; Introduction The atomic layer deposition (ALD) of cobalt films is an ongoing topic of interest [1]. Cobalt thin and ultrathin films play an important role in current generations of integrated circuits [2]. Compared to copper, the metal offers a greater

Molecular nanoarchitectonics: unification of nanotechnology and molecular/materials science

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2023, 14, 434–453, doi:10.3762/bjnano.14.35

• . Unlike conventional solution synthesis, low-temperature local probe chemistry allows for a free control of the radical state. This kind of local probe chemistry as a synthesis technique opens up the possibility of nanoarchitectonics synthesis of carbon nanomaterials. The tip-induced addition of single

• other words, a controlled addition reaction in a single molecule adsorbed on a surface by a local probe at low temperature was demonstrated. Long-lived radicals could be obtained, and C60 molecules could be selectively added to the sites. Such direct addition reactions enable the synthesis of single

• . Foster, Kawai, and co-workers have investigated the zero-bias peak at the center of an armchair-type graphene nanoribbon on a AuSix/Au(111) surface using a combination of low-temperature scanning tunneling microscopy/spectroscopy and density functional theory calculations [116]. The zero-bias peak at the

Polymer nanoparticles from low-energy nanoemulsions for biomedical applications

• Santiago Grijalvo and
• Carlos Rodriguez-Abreu

Beilstein J. Nanotechnol. 2023, 14, 339–350, doi:10.3762/bjnano.14.29

• temperature [9]. At low temperature, that is, below the so-called hydrophilic/lipophilic balance (HLB) temperature (THLB), the poly(oxyethylene) (POE) chain is highly hydrated, and therefore these surfactants self-assemble at interfaces with positive curvature and are able to form O/W droplets. At

• formulate a hydrophobic (oil) phase with the polymer of choice dissolved in a volatile solvent. Then, the volatile solvent can be evaporated from the nanoemulsion droplets under vacuum (that is, at relatively low temperature), and polymer nanoparticles are obtained in the suspension. It is to be noted that

Upper critical magnetic field in NbRe and NbReN micrometric strips

• Zahra Makhdoumi Kakhaki,
• Antonio Leo,
• Federico Chianese,
• Loredana Parlato,
• Giovanni Piero Pepe,
• Angela Nigro,
• Carla Cirillo and
• Carmine Attanasio

Beilstein J. Nanotechnol. 2023, 14, 45–51, doi:10.3762/bjnano.14.5

• case of NbReN. Keywords: non-centrosymmetric superconductors; Pauli and orbital contribution; upper critical fields; Werthamer–Helfand–Hohenberg theory; Introduction Superconducting films of NbRe and NbReN have recently received great attention in the field of low-temperature electronics as suitable

• resistance at 10 K. Results and Discussion Figure 1 displays the normalized resistive transitions in zero magnetic field of the NbRe and NbReN microstrips. The critical temperature, the low-temperature resistivity, and the residual resistivity ratio (RRR) are reported for both microstrips in Table 1. The RRR

Two-step single-reactor synthesis of oleic acid- or undecylenic acid-stabilized magnetic nanoparticles by thermal decomposition

• Mykhailo Nahorniak,
• Pamela Pasetto,
• Jean-Marc Greneche,
• Volodymyr Samaryk,
• Sandy Auguste,
• Anthony Rousseau,
• Nataliya Nosova and
• Serhii Varvarenko

Beilstein J. Nanotechnol. 2023, 14, 11–22, doi:10.3762/bjnano.14.2

• predominant product from Fe(III) acetylacetonate decomposition at a relatively low temperature range of 110–120 °C (see Figure S1 in Supporting Information File 1) [25]. The reaction of the ligand replacement is an equilibrium reaction. Therefore, acetylacetone must be removed from the reaction zone to shift

Observation of collective excitation of surface plasmon resonances in large Josephson junction arrays

• Roger Cattaneo,
• Mikhail A. Galin and
• Vladimir M. Krasnov

Beilstein J. Nanotechnol. 2022, 13, 1578–1588, doi:10.3762/bjnano.13.132

• the source of approx. 100 μW, taking into account losses on the way to the detector via diffraction on optical windows and a set of low-temperature MW filters (Zitex). Such an estimation indicates that the absorption efficiency γ of our detector is indeed not far from the optimal. However, the overall

Structural studies and selected physical investigations of LiCoO₂ obtained by combustion synthesis

• Monika Michalska,
• Paweł Ławniczak,
• Tomasz Strachowski,
• Adam Ostrowski and
• Waldemar Bednarski

Beilstein J. Nanotechnol. 2022, 13, 1473–1482, doi:10.3762/bjnano.13.121

• -ray experiments. Therefore, the assumption that the two different nickel complexes are derived from the crystallites and the surface can probably be rejected. The second reason why two complexes are visible in the EPR spectra is the assumption that two LCO phases are formed during the synthesis: a low

• -temperature cubic phase (LT-LCO) and a high-temperature trigonal phase (HT-LCO) [64][65]. In this case, Ni3+ (I) in the axial symmetry could be attributed to the cubic phase, and the non-axial complex Ni3+ (II) would be characteristic of the trigonal phase. If the nickel admixture is equally well incorporated

Coherent amplification of radiation from two phase-locked Josephson junction arrays

• Mikhail A. Galin,
• Vladimir M. Krasnov,
• Ilya A. Shereshevsky,
• Nadezhda K. Vdovicheva and
• Vladislav V. Kurin

Beilstein J. Nanotechnol. 2022, 13, 1445–1457, doi:10.3762/bjnano.13.119

• straight electrodes with niobium JJs have been directly visualized recently using low-temperature scanning laser microscopy [13]. The scans revealed that the standing waves can provide the global coupling of all junctions in the array, that is, extended parts of the array can interact with each other. This

Studies of probe tip materials by atomic force microscopy: a review

• Ke Xu and
• Yuzhe Liu

Beilstein J. Nanotechnol. 2022, 13, 1256–1267, doi:10.3762/bjnano.13.104

• ][24]. Jiménez-Sánchez et al. [25] studied the extraction of Ir clusters from graphene (by indentation) on the surface of Rh(111) to fabricate AFM sharp nano-tips, i.e., with weak van der Waals interactions. Experiments were performed under ultrahigh pressure and low temperature (5 K) conditions using

Role of titanium and organic precursors in molecular layer deposition of “titanicone” hybrid materials

• Arbresha Muriqi and
• Michael Nolan

Beilstein J. Nanotechnol. 2022, 13, 1240–1255, doi:10.3762/bjnano.13.103

• prefer the flat lying configuration on all surfaces. This work shows that the choice of the surface and the metallic precursor has a major impact on the behaviour of organic species. DFT findings provide motivation to develop a low temperature rutile TiO2/titanicone film suggesting that the desired film

• . Based on the calculated energetics we propose that a low temperature rutile TiO2/TiCl4–EG process and rutile TiO2/TiCl4–GL process can lead to thicker hybrid films. Computational Methods All DFT calculations in this work were performed using the Vienna Ab initio Simulation Package (VASP) version 5.4 [49

• SiO2 membrane [27] and ≈4.6 Å/cycle at 90 °C in Si(100) wafers [30]. We note the relatively low temperature of the titanicone deposition in refs. [27][30] which may prevent the double reaction with EG. For the TiCl3–GL model, the distance between Ti and O in the Ti–O–CH2CH2OHCH2–O fragment (GL in the

A cantilever-based, ultrahigh-vacuum, low-temperature scanning probe instrument for multidimensional scanning force microscopy

• Hao Liu,
• Zuned Ahmed,
• Sasa Vranjkovic,
• Manfred Parschau,
• Andrada-Oana Mandru and
• Hans J. Hug

Beilstein J. Nanotechnol. 2022, 13, 1120–1140, doi:10.3762/bjnano.13.95

• carried out under ambient conditions, are challenging to implement. In this article, we describe a cantilever-based low-temperature UHV AFM setup that allows one to transfer the versatile AFM techniques developed for ambient conditions to UHV and low-temperature conditions. We demonstrate that such a

• attractive or repulsive inter-atomic forces occur between tip apex atom and atoms at the surface. In recent years, functionalizing the tip apex with a lowly coordinated atom/molecule resulted in exceptional submolecular resolution at low temperature [8][9][10][11]. Tuning fork AFM has become increasingly

• -based AFM instrument, which is not only optimized for atomic resolution work, but also permits high-bandwidth AFM operation and, thus, at least in principle, the implementation of more complex AFM operation modes (typically used for ambient environment AFM) also under UHV and low-temperature conditions

Efficiency of electron cooling in cold-electron bolometers with traps

• Dmitrii A. Pimanov,
• Vladimir A. Frost,
• Anton V. Blagodatkin,
• Anna V. Gordeeva,
• Andrey L. Pankratov and
• Leonid S. Kuzmin

Beilstein J. Nanotechnol. 2022, 13, 896–901, doi:10.3762/bjnano.13.80

• due to problems of dilution fridges at low gravity. Electron cooling is also important for ground-based telescopes equipped with 3He cryostats being able to function at any operating angle. This work is aimed at the investigation of electron cooling in the low-temperature range. New samples of cold

• from 100 to 25 mK due to lower Andreev currents, thus decreasing our previous threshold [7] of 42 mK in the low-temperature range. For a better determination of the parameters, we have improved our fitting algorithm that takes into account both the leakage and Andreev currents and the sixth power of

• phonon and electron temperatures. The algorithm is able to describe the parameters of the measured sample with high accuracy, as it can be seen from comparison of experimental and theoretical current–voltage characteristics. While the studied sample demonstrates efficient cooling in the low-temperature

Ultrafast signatures of magnetic inhomogeneity in Pd_1−xFe_x (x ≤ 0.08) epitaxial thin films

• Andrey V. Petrov,
• Sergey I. Nikitin,
• Lenar R. Tagirov,
• Amir I. Gumarov,
• Igor V. Yanilkin and
• Roman V. Yusupov

Beilstein J. Nanotechnol. 2022, 13, 836–844, doi:10.3762/bjnano.13.74

• inhomogeneities. The low-temperature fraction of the residual paramagnetic phase can be deduced from the magnitude of the slow reflectivity relaxation component. It is estimated as ≈30% for x = 0.038 and ≈15% for x = 0.062 films. The minimal iron content ensuring the magnetic homogeneity of the ferromagnetic

Efficient liquid exfoliation of KP₁₅ nanowires aided by Hansen's empirical theory

• Zhaoxuan Huang,
• Zhikang Jiang,
• Nan Tian,
• Disheng Yao,
• Fei Long,
• Yanhan Yang and
• Danmin Liu

Beilstein J. Nanotechnol. 2022, 13, 788–795, doi:10.3762/bjnano.13.69

• . For the Raman tests, KP15 samples were spun on SiO2(300 nm)/Si substrates. The excitation wavelength used was 532 nm, the spot size was approx. 1 μm, and the laser power was kept below 20 μW. For low-temperature Raman measurements, a Linkam THMS600 cryostat cooled by liquid nitrogen was used to

Recent advances in nanoarchitectures of monocrystalline coordination polymers through confined assembly

• Lingling Xia,
• Qinyue Wang and
• Ming Hu

Beilstein J. Nanotechnol. 2022, 13, 763–777, doi:10.3762/bjnano.13.67

• to form monocrystalline coordination polymers embedding a fast electron transfer route [110]. The mixed ion-electron of Prussian blue crystals could be significantly enhanced under low temperature (i.e., −20 °C), which is important for the use of batteries in cold regions. To encapsulate conductive

Experimental and theoretical study of field-dependent spin splitting at ferromagnetic insulator–superconductor interfaces

• Peter Machon,
• Michael J. Wolf,
• Detlef Beckmann and
• Wolfgang Belzig

Beilstein J. Nanotechnol. 2022, 13, 682–688, doi:10.3762/bjnano.13.60

• boundaries between superconducting and normal state, with the superconducting phase at low temperature and small δφ. In general, the critical value δφc increases with decreasing ε’. For small ε’, spin mixing can no longer completely suppress superconductivity for T = 0 (note that the boundary conditions are

• periodic in δφ and hence the maximum spin mixing is reached at δφ = π). For small ε’ or high temperature, the phase transition is of second order. For larger ε’ and low temperature, the phase transition becomes of first order. In this case, the self-consistency relation becomes multi-valued, and a

Quantitative dynamic force microscopy with inclined tip oscillation

• Philipp Rahe,
• Daniel Heile,
• Reinhard Olbrich and
• Michael Reichling

Beilstein J. Nanotechnol. 2022, 13, 610–619, doi:10.3762/bjnano.13.53

• sensor often used in low-temperature environments (tuning fork sensor [21] with f0 = 30 kHz, k0 = 1800 N/m, and A = 0.45 nm). However, similar effects can be present when using parameters for other sensors as well. Frequency shift Δf data are calculated with the piezo axis located at xts = yts = 0 and

Influence of thickness and morphology of MoS₂ on the performance of counter electrodes in dye-sensitized solar cells

• Lam Thuy Thi Mai,
• Hai Viet Le,
• Ngan Kim Thi Nguyen,
• Van La Tran Pham,
• Thu Anh Thi Nguyen,
• Nguyen Thanh Le Huynh and
• Hoang Thai Nguyen

Beilstein J. Nanotechnol. 2022, 13, 528–537, doi:10.3762/bjnano.13.44

• %), valeronitrile (CH3(CH2)3CN, 99.5%), chloroplatinic acid hexahydrate (H2PtCl6·6H2O, ≥37.50% Pt), sulfuric acid (H2SO4, 95–98%), polyvinylpyrrolidone (PVP, (C6H9NO)n, average Mw 10,000), and sodium borohydride (NaBH4, 99%) were purchased from Sigma-Aldrich (Germany). Low-temperature thermoplastic sealant (Surlyn

Zinc oxide nanostructures for fluorescence and Raman signal enhancement: a review

• Ioana Marica,
• Fran Nekvapil,
• Maria Ștefan,
• Cosmin Farcău and
• Alexandra Falamaș

Beilstein J. Nanotechnol. 2022, 13, 472–490, doi:10.3762/bjnano.13.40

• deposition followed by a modified low-temperature solution approach consisted of long ZnO whiskers and numerous stacked ZnO nanoflakes, with plenty of corners and edges where Ag NPs could be deposited. Further hydrogenation was introduced in order to increase the surface area of ZnO nanostructures and led to

Controllable two- and three-state magnetization switching in single-layer epitaxial Pd_1−xFe_x films and an epitaxial Pd_0.92Fe_0.08/Ag/Pd_0.96Fe_0.04 heterostructure

• Igor V. Yanilkin,
• Amir I. Gumarov,
• Gulnaz F. Gizzatullina,
• Roman V. Yusupov and
• Lenar R. Tagirov

Beilstein J. Nanotechnol. 2022, 13, 334–343, doi:10.3762/bjnano.13.28

• .13.28 Abstract We have investigated the low-temperature magnetoresistive properties of a thin epitaxial Pd0.92Fe0.08 film at different directions of the current and the applied magnetic field. The obtained experimental results are well described within an assumption of a single-domain magnetic state of

A broadband detector based on series YBCO grain boundary Josephson junctions

• Egor I. Glushkov,
• Alexander V. Chiginev,
• Leonid S. Kuzmin and
• Leonid S. Revin

Beilstein J. Nanotechnol. 2022, 13, 325–333, doi:10.3762/bjnano.13.27

• used as an element simulating the Josephson junction. It is known [17][24] that the impedance of the HTSC JJ is low, which makes the development of HTSC detectors and mixers difficult in comparison with low-temperature superconductor Josephson junction analogues. Figure 2 shows the dependence of the